Ammonia gas is a chemical compound comprised of one nitrogen and three hydrogen atoms commonly referred to as the ammonia molecule with the formula NH3. In its pure form, ammonia is a colorless gas, but is easily identifiable by smell, as it has a pungent odor. Ammonia is normally found as a gas, which is caustic and harmful with long-term exposures, requiring a hazardous safety permit.
Ammonia gas is commonly found in the production of fertilizers, refrigerants and cleaning solutions, however, you are likely to smell it well before it will be harmful to you. The degree of danger that ammonia gas poses varies significantly depending on how much is present, and how long you've been exposed for.
Industrial ammonia production is one of the highest for inorganic chemicals with numerous large-scale ammonia plants worldwide producing 235 million tones in 2021. Ammonia produced industrially through the Haber-Bosch process, which combines nitrogen from the air with hydrogen, typically derived from natural gas, under high pressure and temperature in the presence of a catalyst.
It's important to note that ammonia occurs naturally in the environment, such as in soil and water. However, human activities, particularly industrial processes, have increased the amount of ammonia released into the atmosphere. This can contribute to air pollution and acid rain.
In the human body, ammonia is a byproduct of protein metabolism. Blood ammonia levels are closely monitored as elevated levels can indicate liver dysfunction or other medical conditions.
Ammonia Toxicity: Exposure to high ammonia concentration can be harmful to human health. Inhalation of ammonia gas can irritate the respiratory tract, causing coughing, wheezing, and difficulty breathing. In severe cases, it can lead to pulmonary edema, a condition where fluid accumulates in the lungs.
Colorless
Gas state
Compressed
Toxic
Flammable
Corrosive
Lighter than air
Water soluble
Explosive (at high concentrations and confined spaces)
Pungent, suffocating odor
Can decompose at high temperatures forming very flammable hydrogen gas
Ammonia based fertilizers and agricultural land management can cause emissions of nitrous oxide.
Ammonia molecules have a trigonal pyramid shape
OTHER NAMES: Anhydrous ammonia, ammonia, azane, hydrogen nitride
CAS 7664-41-7
Farms: Ammonia produced by compost piles on mushroom farms can generate ammonia gas. Manure pits and any indoor or confined spaces where farm animals are kept can also contain ammonia gas.
Water treatment: Ammonia is used to produce monochloramine which is used as a disinfectant.
Refrigeration Systems: Ice rinks, breweries, beverage manufacturing, and ice manufacturing plants use liquid ammonia, or aqueous ammonia - NH3(aq). If it leaks, it becomes ammonia gas, resulting in potentially hazardous ammonia emissions.
Fertilizers and Cleaners: Liquid ammonia is often diluted and combined with other chemicals, frequently forming solutions called ammonium hydroxide. This diluted form is used in household cleaning products, with a potential for ammonia emissions during use.
Ammonium salts may form when ammonia reacts with various acids, impacting both safety and environmental handling measures. Some manufacturing processes combine ammonia with hydrochloric acid to produce ammonium chloride.
May be exposed to ammonia while using cleaning products that contain ammonia.
Other sources of occupational exposure include the silvering of mirrors, gluemaking, tanning of leather, and around nitriding furnaces.
Ammonia is produced as a by-product in coal distillation and by the action of steam on calcium cyanamide, and from the decomposition of nitrogenous materials.
Ammonia is produced naturally in soybean, evening-primrose seeds, lambs quarter, and tobacco leaves.
Type: Electrochemical
Range: 0-100 ppm (0.1 ppm resolution)
High Range: 0-500 ppm (1 ppm resolution)
Low Alarm: 25 ppm
High Alarm: 50 ppm
STEL — 15 minute — Short Term Exposure Limit: 35 ppm
TWA — 8 hour time weighted average: 25 ppm
https://www.ccohs.ca/oshanswers/chemicals/chem_profiles/ammonia.html
https://www.health.ny.gov/environmental/emergency/chemical_terrorism/ammonia_tech.htm
https://www.worksafebc.com/en/health-safety/hazards-exposures/ammonia
https://www.foodmanufacturing.com/facility/article/21103964/ammonia-and-the-associated-risks-of-confined-space-entry-incidents-for-food-refrigeration
https://lpelc.org/wp-content/uploads/2019/03/Section-5-Fact-Sheet-Manure-Gases.pdf
https://www.chemicalbook.com/ProductChemicalPropertiesCB9854275_EN.htm